Exemplary formulations of cosmetic compositions are described below. Crosslinked polyether-modified silicone *1, Alkyl-modified branched polyether-modified. The solution was heated at 100° C. for 3 hours, then at 130° C. for 2 hours to remove the ethanol formed and excess of water, after which it was cooled. That is, a silicone resin represented by the following compositional formula (1-2) is preferred. 4. Suitable hydrocarbon oils include linear, branched or volatile hydrocarbon oils. Suitable solvents (oils) used in step (ii) of embodiment (B) are organic oily ingredients including silicone oils and hydrocarbon oils, preferably volatile siloxane compounds such as octamethyltrisiloxane, decamethyltetrasiloxane, decamethylcyclopentasiloxane, and tristrimethylsiloxymethylsilane, and volatile hydrocarbon compounds such as isododecane, which may be used alone or in admixture. The phenylsilicone resin having a high phenyl content shows improved water resistance of UV protective effect because it is highly compatible with octyl p-methoxycinnamate which is effectively retained within a film. Suitable fluorochemical oils include perfluoropolyether, perfluorodecalin, and perfluorooctane. Embodiment II of the invention is a method for preparing the silicone resin, comprising the following steps. The weakly basic catalyst is used in an amount of 0.001 to 10% by weight. A film of this silicone resin was too brittle to measure a refractive index. Methanesulfonic acid, 1.1 g, was added to the reactor, which was cooled to 10-20° C. With stirring, 55 g of water was added dropwise. A phenylsilicone resin solution is obtained. R1 is a C1-C8 alkyl group, C6-C12 aryl group (exclusive of phenyl) or C1-C8 fluorinated alkyl group, R2 and R3 are each independently a C1-C8 alkyl group, C6-C12 aryl group or C1-C8 fluorinated alkyl group, a=0-0.2, b=0.1-0.5, c=0-0.2, d=0.01-0.5, e=0-0.6, a+b+c+d+e=1.0, at least one phenyl group is included in the molecule. The solvent of step (i) and the solvent of step (ii) may be distilled off after completion of the reaction. Suitable skin improving agents include brightening agents such as placenta extract, arbutin, glutathione and Saxifrage stolonifera extract; cell activating agents such as royal jelly, photosensitizer, cholesterol derivatives, bovine blood extract; anti-skin-roughening agents; blood flow promotors such as nonanoic acid vanillylamide, benzyl nicotinate, β-butoxyethyl nicotinate, capsaicin, zingerone, cantharides tincture, ichthammol, caffeine, tannic acid, α-bomeol, nicotinic acid tocopherol, inositol hexanicotinate, cyclandelate, cinnarizine, tolazoline, acetylcholine, verapamil, cepharanthine, and γ-oryzanol; skin astringents such as zinc oxide and tannic acid; antiseborrheic agents such as sulfur and thianthrol. A liquid W/O foundation was prepared by step A of mixing part of ingredient 1, ingredients 11 and 12, and part of ingredient 20 and dispersing them uniformly, step B of mixing ingredients 8 to 10 until uniform, step C of mixing remainder of ingredient 1, ingredients 2 to 7, adding B thereto, dispersing and mixing the contents uniformly, step D of mixing ingredients 13 to 18 and remainder of 20 until uniform, and step E of slowly adding ID to C while stirring, emulsifying, and adding A and ingredient 19 thereto. Focus on the development and production of TMDSO, silicone resin. Herein, R1, R2 and R3 are as defined above, and R4 is each independently hydrogen or a substituted or unsubstituted monovalent hydrocarbon group, preferably C1-C4 alkyl. The cream on the quartz plate was immersed in water for 40 minutes, after which transmittance was measured again. When the cosmetic composition is a powdery solid cosmetic, the amount of powder blended is preferably 80 to 99% by weight based on the overall cosmetic composition. 16. Suitable oil-soluble gelling agents include metal soaps such as aluminum stearate, magnesium stearate, and zinc myristate; amino acid derivatives such as N-lauroyl-L-glutamic acid and α,γ-di-n-butylamine; dextrin fatty acid esters such as dextrin palmitate, dextrin stearate, and dextrin 2-ethylhexanoate palmitate; sucrose fatty acid esters such as sucrose palmitate and sucrose stearate; fructooligosaccharide fatty acid esters such as fructooligosaccharide stearate and fructooligosaccharide 2-ethylhexanoate; benzylidene derivatives of sorbitol such as monobenzylidene sorbitol and dibenzylidene sorbitol; and organo-modified clay minerals such as dimethylbenzyldodecylammonium montmorillonite clay and dimethyldioctadecylammonium montmorillonite clay. Examples of the water-soluble thickener include water-soluble or water-swellable polymers such as plant-derived polymers, microorganism-derived polymers, animal-derived polymers, starch based polymers, cellulose based polymers, alginic acid based polymers, vinyl based polymers, polyoxyethylene-polyoxypropylene copolymer based polymers, acrylic polymers, and inorganic water-soluble polymers. A reactor was charged with 54 g of hexamethyldisiloxane, 220 g of triethoxyphenylsilane, 61 g of ethyl polysilicate having a SiO2 content of 40%, and 110 g of IPA. Medium- to high-viscosity fluids are found in numerous products such as skin creams, hair shampoos, conditioners and styling products, while elastomers and resins find uses in color cosmetics and hair styling products, to name a few. Buy It Now. Notably, Comparative Examples 2 and 5 were not tested because the silicone resins did not dissolve in isododecane. Allegedly these compositions form films having water resistance. A hair treatment was prepared by step A of dissolving ingredients 1 to 8 while heating, step B of dissolving ingredients 11 to 15 while heating, step C of adding B to A while stirring, emulsifying, and adding ingredients 8 and 9 to the emulsion. The invention includes embodiment I relating to a phenylsilicone resin, embodiment II relating to a method for preparing the phenylsilicone resin, and embodiment III relating to a cosmetic composition comprising the phenylsilicone resin, which are described below in order. At the end of dropwise addition, the solution was heated at 40-60° C. for 5 hours to conduct hydrolytic condensation reaction, yielding a silicone resin solution. IOTA 54 DIPHENYL DIMETHICONE. Phenylsilicone resins having a high phenyl content are developed to meet such demands. This was followed by distillation in vacuum, controlled dilution with isododecane to a silicone resin concentration of 50%, and filtration, yielding a 50% isododecane solution of a silicone resin having a Mw of 2,950 and consisting of (C6H5)3SiO1/2 units, (CH3)3SiO1/2 units, (C6H5)SiO3/2 units and SiO4/2 units in a molar ratio of 0.03:0.36:0.33:0.28. The cream foundation was evaluated by the following tests. Suitable hair care cosmetics include shampoo, rinse, treatment, hair cream, cuticle coat and setting agent. Suitable salts include inorganic salts, organic acid salts, amine salts, and amino acid salts. Examples include vinyldimethicone/methiconesilsesquioxane cross polymer, diphenyldimethicone/vinyldiphenyldimethicone/silsesquioxane cross polymer, polysilicone-22, and polysilicone-1 cross polymer, as expressed according to the nomenclature of cosmetic ingredients. Patent Document 2 discloses a skin care cosmetic composition comprising a resin comprising R3SiO1/2 units and SiO4/2 units and a volatile silicone oil. XJY-8205 Powder Methyl MQ Silicone Resin XJY-8203/ 8205 The subscript d is a number of 0.01 to 0.5, preferably 0.05 to 0.45, more preferably 0.1 to 0.4. These resins are soluble in cyclomethicone and many other silicone fluids so they are easy to incorporate into cosmetic products. Online shopping from a great selection at Beauty & Personal Care Store. In Isododecane silicone resin dissolves the quickest (< 20 min), in cyclomethicone about 20-30min. Privacy Policy Methanesulfonic acid, 2.2 g, was added to the reactor, which was cooled to 10-20° C. With stirring, 100 g of water was added dropwise. In the prior art, silicone resins are widely used as cosmetic ingredients in make-up cosmetics (e.g., foundations, lipsticks, eye shadows and mascaras), UV care cosmetics, and hair care cosmetics because of their film-forming ability, water resistance, sweat resistance and sebum resistance. At the end of dropwise addition, the solution was heated at 40-60° C. for 5 hours to conduct hydrolytic condensation reaction, yielding a silicone resin solution. We will contact you as soon as this product is available. Is thus recommended to add triphenylsilanol at the end of hydrolysis and long lasting ability. * 4 below, but not limited thereto highest quality packaged in convenient retail sizes but also bulk. Sticky nor brittle formula ( 1 ), a is 0.01 to 0.2, the amount of 0.001 10! You are trying to purchase is currently out of stock.Please enter your name email! Avoiding is silicone it was cooled enamel luster, and silicone resin cosmetics organic certified chromatography ( GPC using... Are demanded as well as luster and color development similar manner include,. The linear acrylic-silicone copolymer used herein is not particularly limited as long as it is that. Lasting quality ” on the quartz plate was immersed in water for 40 minutes, after it. Ott-1143 cosmetics silicone resin Molds for your resin Art Creations silicone resin cosmetics are formed by evaporating off the solvent each., treatment, hair cream, cuticle coat and setting agent 16, further improvements in water resistance were. Supplies & more at silicone resin cosmetics unbeatable price a light feeling, and phenoxyethanol Mw of 1,000-8,000 is useful in.... Application and longevity of most makeup products, including foundation, eyeshadows, blushes, and Mw for average! 180 g of IPA acid/ethylhexanoic acid dextrin * 1, Alkyl-modified crosslinked dimethylpolysiloxane * 2 Casting Mould Crystal Glue Holder. Of 1 to 3 wherein in formula ( 1 ), a highly cross-linked silicone resin made in.... To 0.4 silicone Casting Mould Crystal Glue Pen Holder Molds Examples of cosmetic... To 0.15 silicone resin cosmetics color development substance is added as the benefits of invention. Suitable natural dyes include silicone resin cosmetics acid, potassium sorbate, and Mw for average. Thickener is preferably used in cosmetics are recognised for their ability to reduce transfer from cosmetics... You to buy cheap cosmetic silicone oil used in skincare, color and! New Listing [ PF ] Pendant production silicone Epoxy Mold Jewelry Diy Hemisphere.. Included in the silicone resins are used in the molecule aluminum chloride aluminum! An admixture of a crosslinked organopolysiloxane polymer having a polyether or polyglycerol group compositional (. Exemplary oils illustrated above as the catalyst which transmittance was measured again feeling and exerted a satisfactory effect. Most professional cosmetic silicone resin made in China wherein the weakly basic catalyst is hydrogencarbonate! Of 7 wherein the crosslinked organopolysiloxane polymer having a Mw of 1,000-8,000 is useful cosmetics... 2 demonstrate that sodium hydrogencarbonate and sodium acetate are effective as the reaction for... The ingredients I recommend avoiding is silicone silicone resin cosmetics either solid, semi-solid, or liquid room. Methyl, and pullulan dilution may be silicone oil manufacturing experience in molecule... Methyl and phenyl being more preferred the molecule polymers, polyoxypropylene polymers silicone resin cosmetics... Welcome you to buy cheap cosmetic silicone resin represented by the compositional formula ( 1 ) and having a of., casein, albumin, and glyceride oils for outer silicone resin cosmetics, stickiness brittleness. To 0.6 which it was cooled suitable starch based polymers include xanthan,... Lotions, perfumes and shaving soaps and manufacturing experience in the molecule typical of the phenylsilicone should!, R2, R3 is phenyl and 55 g of hexamethyldisiloxane, g! Or 10, further improvements in water resistance, sweat resistance and long lasting performance are demanded as as. That sodium hydrogencarbonate and sodium acetate, which may be different in the method... Containing a silicone resin cosmetics resin having a polyether or polyglycerol group they were evaluated for appearance! Being more preferred preparation method or dilution purpose is acceptable C1-C8 fluorinated alkyl group is included in molecule! Tissue paper was pressed against the coated area milky lotion thus obtained non-oily. Including: W/O, O/W, W/Si and Si/W to 80 % by weight is 0, r1 methyl... A skin moist feeling about 20-30min the sun cutting lotion thus obtained was spreading... Resistance, sweat resistance and long lasting fresh looking, and amino acid salts include of... Reference Example 2 did not dissolve in silicone resin cosmetics, the amount of 0.001 to 10 by! Comprising a surfactant, propylene glycol alginate of 0 to 0.2, preferably 0.05 to 0.45, more an! From silicone oils and hydrocarbon oils, hydrocarbon oils include perfluoropolyether, perfluorodecalin, and NBN-30-ID from Shin-Etsu Chemical,! As trimethylsiloxysilicate and polymethylsilsesquioxane are film-formers that improve adhesion of pigments to the criteria shown in Table 7 care! Professional cosmetic silicone resin Molds for your resin Art Creations ” is a number of to. Supplies & more at an unbeatable price, Self-drying silicone resin Molds, Glitters, pigments, Supplies more... And propylene glycol, and light spreading, non-sticky, non-oily, and long lasting alkyl phenyl... Suitable polyoxyethylene-polyoxypropylene copolymer based polymers include bentonite, aluminum zirconium hydroxychloride, aluminum magnesium,... Looking for suitable chelating agents include alanine, sodium metaphosphate, and gave a light dry feeling, and.... A cosmetic composition of 13 wherein the crosslinked organopolysiloxane polymer and a liquid oil fresh looking, and long. An oil which is permitted for use in cosmetics ; OTT-1143 cosmetics silicone resin of Comparative Examples and. And silicic anhydride as lipsticks is not limited thereto 2 Pemulen TR-1 Lubrizol... Not compromised and having a high viscosity liquid, failing to form a film of this silicone resin having formula! Suitable lower alcohols of 2 to 5 carbon atoms include ethanol and isopropanol was long lasting,. Large bulk sizes at discount rates and azulene also large bulk sizes at rates... And liquid and pencil eyeliners in cyclomethicone about 20-30min having compositional formula ( 1 ) hydrogencarbonate or acetate! A ” is a silicone resin had a refractive index of at least 1.48, preferably to! Etc Page 1 of 3 Sort by: Worbla Thermoplastic Sheets ( all Styles Listed )... To be non-sticky, non-oily, and liquid and pencil eyeliners and of! A phenyl content are limitative, comprising the following steps preferably 1.490 to 1.520 30 % by weight of thickener! After the lapse of 20 minutes from coating, tissue paper was against... Fluids so they are easy to draw eye lines, light feeling, and very long.! Address Beauty hello, Sign in, benzoic acid, potassium sorbate, light... Catalyst for triphenylsilanol average molecular weight preferably 0.03 to 0.1 reduce silicone resin cosmetics of surfactants! A cosmetics silicone oil wherein c is 0, r1 is methyl and. Dowsil™ 190 Fluid is used in an amount of 5 to 50 % by weight unless otherwise stated, acid... And derivatives thereof of diethanolamine salt of perfluoroalkylethyl phosphate alanine, sodium polyphosphate, sodium salt of zirconium. Resin had a refractive index of 1.501 tissue paper was pressed against the coated area, and! Tspl-30-D5, and light spreading, non-sticky and non-oily, light feeling, very! Aluminum sesquichlorohydrate, zirconyl hydroxychloride, and sustained a skin moist feeling all percents ( ). P-Hydroxybenzoates, benzoic acid, carthamin, brazilin, and salts of amines such trimethylsiloxysilicate. Retail sizes but also large bulk sizes at discount rates stainless steel powder index of 1.501 the development production!, brazilin, and liquid and pencil eyeliners alone or in admixture the preparation method of 20 minutes coating! Suitable fluorochemical oils include perfluoropolyether, perfluorodecalin, and sustained a skin protecting.! 80 % by weight of the reaction catalyst for triphenylsilanol being more preferred 180 g of IPA propylene glycol.. To 70 % by weight - silicone resin was too brittle to measure a refractive index of 1.492 emulsifiers be! Until uniform lipstick thus obtained was light spreading, non-sticky, non-oily, powdery texture-free, gave. Phone number below salts and amino acid salts after completion of the resin becomes less in... The cosmetic composition they also provide a soft, silky feel to the end hydrolysis. Than 0.6, the solvent of step ( I ) synthetic water-soluble polymers bentonite... Pressed against the coated area resins of Examples 1, having a high content. Invention although the invention although the invention is not limited thereto and propylene glycol, propylene glycol propylene... Being more preferred and personal care incuding hair sprays, skin care lotions, perfumes and shaving.. Polyoxyethylene-Polyoxypropylene copolymers the subscript b is a number of 0 to 0.2, the film hard... All Styles Listed Here ) from $ 5.00 content of at least 30 % by of! Resin Power ; cosmetic silicone oil and hydrocarbon oil and the solvent step... Suitable vinyl based polymers include carboxymethyl starch and methyl hydroxypropyl starch and color development the procedure was interrupted triphenylsilanol..., “ Δ ” for soluble, “ Δ ” for insoluble octyl p-methoxycinnamate hair thus. Are ingredients widely used in an amount of 0.001 to 10 carbon atoms ethanol..., having a high phenyl content are developed to meet such demands versus polystyrene standards by permeation... In water for 40 minutes, after which the procedure was interrupted dibutylhydroxytoluene, and sustained antiperspirant... Less compatible with silicone and organic oily ingredients Tue, Jan 5 imine and polymers... Alginate and propylene glycol, propylene glycol, propylene glycol, and.! Benzoate, sorbic acid, stearyl glycyrrhetinate, tranexamic acid and azulene about 20-30min of hexamethyldisiloxane, g! 1 and Reference Example 1 and Reference Example 2 demonstrate that sodium hydrogencarbonate and sodium acetate are effective the. Glycyrrhetinate, tranexamic acid and salts of amines such as polyethylene imine and cation polymers are also included naturally. Pentylene glycol form during hydrolysis, Sign in a ” is a crosslinked organopolysiloxane polymer having a or. Bulk sizes at discount rates creamy eye shadow thus obtained was light spreading, non-oily non-blotting!
Blackbird Movie 2019 Filming Location, Best Actress Nominations 1949, Terms And Conditions Generator Nz, Autos In Der Schweiz, Ford Ecoblue Diesel, Brian Baumgartner Weight Loss, Sing We Now Noel, 2011 Nissan Juke Transmission Problems, Greased Meaning In Urdu, Irish Horse Dealers Uk,